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We observed that supra-particles infused with water had different wettability and attachment positions at the oil–water interface compared with the same particles infused with oil. We report for the first time results of an MRI study of supra-particles attached to an air–water or an oil–water interface, which indicated that only the surface layer of the building block particles attaches to the liquid interface while the pore fluid was not displaced by the outer fluid. We characterised the surface morphology and the inner structure of supra-particles by SEM imaging. This preparation technique allowed limited control over the porosity of the supra-particles by varying the initial concentration of the latex particle suspension, the rate of evaporation and the annealing temperature. We controlled the supra-particle size by varying the initial volume of the latex suspension drop, the latex particle concentration and the drop evaporation temperature. Spherical porous supra-particles were produced above 40 wt% initial concentration of the latex particles in the suspension, which had a rough surface, with a porous and amorphous structure. It was found that the emulsions exhibited a shear thinning with yield stress non-Newtonian rheological behavior and that the flow curves were well. Even at these low particle concentrations (0.9 vol.), the dispersions exhibit a large variation in low shear viscosity with salt concentration, due to the formation of a network. We annealed the dried supra-particles at the polymer's glass transition temperature to fuse partially their latex particle building blocks. The dispersion rheology was measured at the same particle and salt concentrations as in the emulsions. We used a simple method for fabrication of millimetre-sized spherical porous supra-particles from much smaller monodisperse latex microparticles as building blocks by evaporation of a polystyrene sulphate latex suspension on a hot super-hydrophobic surface. Title Stokesian dynamics simulations of interfacial colloidal aggregation under shear. Particle-stabilised or Pickering emulsions are versatile systems. Finally, the importance of using Pickering emulsions to carry out reactions in flow and in multi-step cascade systems is highlighted with various examples to support the benefits of transferring this technology to industrial processes.We prepared model porous composite supra-particles and investigated the effect of the initial infused fluid phase on their attachment at the liquid–fluid interface. Session Emulsions, Foams, and Interfacial Rheology. We find that particle exchange occurs by two routes: firstly, during a period of unbridging and rebridging whose duration can be tuned by varying the wettability of the particles and secondly. A section describing methods for recovering the catalyst is also included, in which various stimuli are discussed. An overview is given regarding the kinds of liquid phases comprising the emulsion system, the different types of solid particle stabilizers (whether they contain catalyst or not) and the catalytic reactions studied. Fig.2 Shear rheological properties of the emulsion sample obtained at. A key aspect of the proposed manufacturing process is the utilization of resins consisting of well-established Pickering emulsions that are stable against shear but also readily flow under low. As the area has advanced rapidly, the intention of this review is to summarize the latest innovations being reported. Fig.1 Appearance of the systems containing 65 water, 35 xylene and 0.5 silica nanoparticles (A) Before shearing (B) and (C) sheared at rotation speeds of 50 r/min, respectively, shearing time: 3 min (D) Pickering emulsion obtained at 24000 r/min is solid-like. In the past 10 years a new application has emerged in the field of catalysis to use them as vehicles to carry out catalytic reactions, allowing a more environmentally friendly process with high conversions and selectivities and important advantages for catalyst recovery. All simulations start from a random mixture of fluids and particles. Particle-stabilised or Pickering emulsions are versatile systems. Snapshots of a 3D Bijel (a) and a Pickering emulsion (b): particles (green).
I’m moving from segmented level to level trying to figure out what the game wants me to do, instead of having fun with everything that I’ve been shown is possible. This often makes Superliminal feel like Portal. You can’t make everything bigger or smaller, and there are doors every so often that block you from bringing your useful soda cans, exit signs, or chess pieces into the next level. The problem is that Superliminal isn’t a sandbox it’s a puzzle game. It feels like a magic trick, but one that I control. I spend my first hour or so with the game making boxes bigger and then smaller again while chuckling to myself. The key mechanicĮverything comes down to the idea of tampering with reality through the use of perspective, which is legitimately very neat. It sounds soothing, right up until it becomes clear that something, somewhere, has gone wrong, and I’m stuck inside a dream that very quickly begins to feel like a nightmare. I don’t know who I am, but I’m clearly here to test a program and learn something in the process. You see, I’m in a therapy session conducted via dreams. It’s not about what’s real, it’s about what looks real. Portraits, seen in the right way, can become doorways to another environment. I can pick it up as if it were a physical object, and now it’s in my hands. If I stand just right, the block looks real. Later, I find an orange block painted on the walls. This is the key mechanic of Superliminal. However, when I turn and place the soda at the end of the hall, I’ve played a clever trick I can now walk towards the soda can to find its grown to a massive size. When I hold the soda in my hands, it’s quite small. I stand in the hallway of a quiet medical facility, and grab a can of soda from a vending machine. Superliminal is a puzzle game in which perception is reality. Nevertheless, low-lying areas that can serve as frost pockets should be avoided, if possible. In North Florida, microsprinkler irrigation for cold protection is imperative, especially for the non-satsuma varieties. Satsuma did not sustain any significant cold injury. The last 10 years have experienced temperatures as low as 15 F, and Navel, Minneola Honeybell and Valencia have not experienced damage other than tip burn. The coldest temperatures recorded in Quincy for the winters of 2015–2016, 2016–20–2108 were 26, 26 and 20 F, respectively. To avoid peel tearing, satsumas must be clipped to be harvested and should be handled with care because they are more prone to bruising than most other types of citrus.Ĭurrently, there is an urgent need to diversify fresh-market citrus in North Florida to include varieties that mature from September through December.Īt the University of Florida Institute of Food and Agricultural Sciences (UF/IFAS) North Florida Research and Education Center in Quincy, many varieties and numbered selections have been under evaluation for up to 13 years. They mature and are harvested during a four-week period centered in mid-November. When properly cold acclimated, satsumas are cold hardy down to about 12 to 14 F. In 2017, the acreage of citrus by county in North Florida was as follows: Gadsden, 120 Jackson, 31 Jefferson, 30 Taylor, 34 Madison, 30 and Suwannee, 20. Satsumas are the most cold-hardy commercial citrus and account for a great majority of the new commercial citrus acreage in North Florida. The relatively mild winter temperatures during the last three decades and the development of microsprinkler irrigation in the early 1990s to reduce the effects of freeze (Figure 2) have led to a resurgence of interest in cold-hardy citrus in North Florida. A young citrus reset covered in ice from microsprinkler irrigation helps reduce cold injury to the tree. The Max pins, we bought in a much larger quantity, to bring the per-item cost down, and used as giveaways at ComicCon, PAX, and other trade shows. The biological weapon was a cocktail napkin with custom printing, like people normally buy for weddings or bar/bat mitzvahs. If we remember correctly, the hypno-glasses were the most expensive item-paper 3D glasses with green swirls silkscreened on the cellophane lenses. We couldn’t afford a lot of customization, so we had to stick to promotional type items that were easy to buy in bulk. Mafia-Free Playland and Casino fridge magnetĮach item had to be flat, inexpensive to produce, and easy to source.Front page of the Alien Love Triangle Times.Inside the envelope were six souvenirs, one for each Season One episode: (Max spent a day hitting people over the head before he returned to the office to file his paperwork.) The date on the Season One Case File is May 11, 2007, one day after the final episode launched on Telltale’s website. This had a blank line for the date, which was stamped separately in red ink using the type of date stamp that’s used in libraries (or used to be, anyway). The outside was hand-stamped with a Freelance Police Case File rubber stamp that we had custom made at a local print shop. The Season One Case File was a 4.75” by 6.5” brown kraft envelope reminiscent of an office folder (or so we hoped). Much to management’s dismay, no money was made on the Season One Case File. Coincidentally, each case file cost almost $5 to produce-and that was before assembly. We sold these for $5, cheap enough for an impulse buy. Instead we came up with the idea of a case file-a packet of Season One souvenirs small and flat enough to fit inside the DVD case. But because the DVD was a freebie, we couldn’t get extravagant with the packaging. Do you have any… nostalgic yet reasonably priced feelies?īecause we were old-school adventure game fans, we wanted Telltale’s physical Sam & Max release to have a big box with feelies inside, to be proudly displayed on a shelf next to Hit the Road and other LucasArts classics. Telltale’s Sam & Max offerings included posters, tee shirts, hats, and a Season One soundtrack.īy far, the most labor-intensive product was the Season One Case File-but it was a labor of love. When it came time to produce those DVDs in the summer of 2007, we decided to add other merchandise to the Telltale store so people could get more for the shipping price they were already paying. So Telltale sweetened the deal by promising a free game DVD to season pass customers for only the price of shipping. The idea of buying a season pass for a game that might never be finished was a turn-off for a lot of people who were otherwise very excited to play a new Sam & Max game. It's Sam and Max's 50th wedding in a bit, so to celebrate, he and Max hold a talk show for their family to attend.When Sam & Max Season One launched in 2006, downloadable games were a new phenomenon and episodic games were even newer. John the Alligator/Shin the Dragon (OC).John the Alligator & Max & Sam (Sam & Max).MrBandwidth Fandoms: Sam & Max (Comics), The Adventures of Sam & Max: Freelance Police (Cartoon), Sam & Max (Video Games) Language: English Words: 1,603 Chapters: 1/1 Kudos: 28 Bookmarks: 1 Hits: 284 (part of a trade with IdyTwisted on Twitter) Series WOULDN'T YOU LIKE TO HEAR SOMETHING STRANGE?Īfter messing around with one of Geek's inventions, Sam and Max find themselves in a dreary, gothic town full of monsters.
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If you promise to stop (by clicking the Agree button below), we'll unblock your connection for now, but we will immediately re-block it if we detect additional bad behavior. Overusing our search engine with a very large number of searches in a very short amount of time.Using a badly configured (or badly written) browser add-on for blocking content.Running a "scraper" or "downloader" program that either does not identify itself or uses fake headers to elude detection. Using a script or add-on that scans GameFAQs for box and screen images (such as an emulator front-end), while overloading our search engine.There is no official GameFAQs app, and we do not support nor have any contact with the makers of these unofficial apps. Continued use of these apps may cause your IP to be blocked indefinitely. This triggers our anti-spambot measures, which are designed to stop automated systems from flooding the site with traffic. 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Gamewalhalla ships exclusively with Bpost. We also have a membership for 3 or 6 months. For a fixed price a year you'll recieve free shipping for all your orders. If you shop regularly at Gamewahalla you may consider buying the Gamewalhalla GO membership. So when ordering multiple items you would pay several times the shipping costs. If Gamewalhalla would offer free shipping we would be obliged to increase the price of each item with a few euros. Free shipping means all prices are prices with shipping prices included. Very simple: free shipping doesn't exist. WHY NO FREE SHIPPING AS A LOT OF OTHER WEBSHOPS DO? As a professional seller we're also legally obliged to add 21% of VAT to these cost that we need to pay to the government. Shipping costs consist out of the costs for the packaking materials (bubble envelopes, envelope boxes, carton boxes) and stamps. The shipping costs depend on the weight/value of your order and to where it needs to be shipped. You'll need your bank card and card reader.Ĭhoose your preferred shipping option when checking out. You'll be redirected to your familiar online banking environment to make the payment. If you're already a customer at the Belfius bank you can pay by our own bank through this payment option. Possibly even the very same day if we receive your payment in time.īelfius Payment Button (Belfius Direct Net) Your order will be shipped within 1 working day. You'll need your bank card and card reader. If you're already a customer at the KBC bank you can pay by our own bank through this payment option. Possibly even the very same day if we receive your payment in time. Make sure to have your bank card and card reader close at hand. After entering your card number and expiration date you will be redirected to your trusted banking environment to carry out the payment. When checking out choose to pay by MisterCash if you'd like to pay with your bank card. There are several banks nearby if necessary. PROCESSING: 1-3 working days depending from which bank the payment comesĪll order can be picked up in our shop where you can pay in cash. Please always add this order number in the communication.īNP Paribas Fortis on the name of GamewalhallaĬommunication: order number + name of the game Place your order on our website and pay afterwards with pc-banking or at the counter of your bank.Īfter completing your order, you'll receive an email with your order number and all payment info. SO IT MAY BE POSSIBLE THAT YOU SEE THIS NAME APPEAR ON YOUR BANK STATEMENTSĪll payments are free. CARD NUMBERS AND OTHER DATA WILL NOT BE SAVEDĪLL ELECTRONIC PAYMENTS ARE PROCESSED BY MOLLIE (). When checking out you can choose the payment method that suits you best.ĪLL ELECTRONIC PAYMENTS TAKE PLACE IN A SECURED ENVIRONMENT. Gamewalhalla offers a wide range of payment options. |
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